https://www.britannica.com/technology/gum-adhesive
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Gum, in botany, adhesive substance of vegetable origin, mostly obtained as exudate from the bark of trees or shrubs belonging to the family Fabaceae (Leguminosae) of the pea order Fabales. Some plant gums are used in the form of water solutions in the manufacture of cosmetics, pharmaceuticals, and foods. When the water evaporates, a film having a considerable adhesive character is formed. Some plant gums, such as gum arabic, dissolve in water to give clear solutions. Other gums, such as gum tragacanth, form mucilages by the absorption of large amounts of water.
A gum is produced by making an incision in the bark of the tree and collecting the exudate repeatedly throughout the season. Gums so obtained consist of small lumps, usually transparent and light yellow. Trees produce gums by a process called gummosis, possibly as a protective mechanism, either after mechanical damage to the bark or after a bacterial, insect, or fungal attack upon it. The Acacia senegal tree yields the greatest amount of gum acacia when it is in an unhealthy condition, and good culture methods reduce the yield.
Gum arabic is the most widely used of the water-soluble gums. True gum arabic is gum acacia; that is, it is produced by species of Acacia. Examples of true gum arabic are gum sudan and gum kordofan, both of which originate in Sudan, and gum senegal, which comes from Senegal. Gum arabic is also collected in northern Nigeria, Libya, Tunisia, and Tanzania. The name gum arabic is sometimes also applied to substitutes for gum acacia, including gum gatti, collected in India.
Gum tragacanth is second in importance commercially; it is produced by several shrubs of the genus Astragalus, principally Astragalus gummifer, native to the arid regions of Iran, Asia Minor, and Greece. The exudate is produced spontaneously on the bark of the shrub, but the yield may be increased by making an incision and driving wooden wedges into it. One of the oldest drugs known, its use dates from pre-Christian times. Gum tragacanth is still used pharmaceutically as a demulcent (coating) and as a binding agent in pill manufacture. In processed foods it is used as an emulsifier and in sauces as a thickener. Gum karaya and carob gum have been used as limited substitutes for gum tragacanth.
Chemically, the plant gums are complex compounds derived from carbohydrates; specifically, they are salts, either potassium, magnesium, or calcium, of acidic polysaccharides, the acidity of which is due to uronic acids in their structure. Rubber, chicle, and other latex products are not true gums. Varnish gums are actually resins and are chemically quite different from plant gums.
